Stable radicals during photodecarbonylations of trityl-alkyl ketones enable solid state reactions through primary and secondary radical centers.
نویسندگان
چکیده
The solid state photoexcitation of several triphenylmethyl-alkyl ketones resulted in the loss of CO and the exclusive formation of radical-radical combination products. Differences in reactivity suggest a stepwise mechanism with the unprecedented formation of primary and secondary radicals in some of the radical pair intermediates in the solid state.
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ورودعنوان ژورنال:
- Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology
دوره 10 11 شماره
صفحات -
تاریخ انتشار 2011